I haven't used ANSYS in a long time, so I can't speak to specifics about the code.
In general terms, I would go about it this way:
1)Model the shaft of the bolt with beam elements.
2)Model the nut and bolt head with solid or plate elements, connecting the beams to the centerpoints using something which distributes the moments from the beams into the solid/shell elements.
3) Model contact between the bolt head and plate structure, and between the nut and plate structure. You may need to also model contact between the connected plate structures, depending on the physics of the problem.
4) Figure out a way to apply the tensile forces to the bolt beams. Some codes have tools to do this automatically. If yours does not, the poor man's way to do this is to assign an initial temperature to the beams, prescribe a coefficient of thermal expansion to the beam material, and then "cool" the beams, thereby invoking tension through thermal contraction. Of course, this only works if you don't some time later in your analysis need to actually evaluate temperature effects on other things.
Brad