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nitrate level detection

nitrate level detection

nitrate level detection

(OP)
I’d like to check for nitrate levels using online optic system.

Nitrates (NO3-) in liquid absorb mostly around 220nm , most water quality devices looking for nitrate check around there.

I found a ~20$ diode that detects down to 215nm.

I can compare the diode signal thru ‘bad’ water with signal thru clean water and subtract but a lot of signal is shared thru both samples (last fig shows both detector response (blue) and nitrate abs (orange) curves)

So I thought to try to limit the source freq. to eg. 240 or below.

There are some specialty LEDs that transmit at around 240 but the’yre around 300$.

So I thought maybe I can frequency-triple a 632nm, HeNe laser , but the crystals involved (BBO,LBO) seem to also be a few hundred $.

I could also try a diffraction grating to select around 220nm from a Xe flashlamp but I’m not sure which kind of grating , they do seem cheap.
Can someone recommend which grating I want (lines/mm and kind of blaze seem to affect efficiency vs wavelength) or an alternate approach.





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