Discharge temperature respective to which equipment???
If you are referring to compressor, this would be my bet:
Propylene has higher MW than N2. If the compression is done with a centrifugal, then in order to keep compression ratio identical you would need to have the machine spin at higher rpm with N2, and you need to make sure you have room for that speed increase, alternatively would could reduce the capacity at identical speed but allowance for doing so is usually limited, or combination of both. Because of the lower MW, all things being kept equal while operating within machine envelop - you would have to expect a lower temperature increase due to compression when running with N2 than when it is with Propylene. Goes without saying that this comment is from a compressor view point. Whether this makes any sense (physically) with respect to your entire system or not, is another story.