Limiting Oxygen Concentration
Limiting Oxygen Concentration
(OP)
Does anybody know where to find the LOC of cyclohexane and acrylic acid?
Is it possible to predict the LOC of an organic compound?
Thanks.
Is it possible to predict the LOC of an organic compound?
Thanks.
RE: Limiting Oxygen Concentration
Write a balanced oxidation reaction equation to CO2 and H2O.
Example: C3H8 + 5O2 --> 3CO2 + 4H2O
LFL of propane = 2.2% in air
2.2 x 5 = 11.0%
MOC of propane = 11.5% by lab determination.
Good luck,
Latexman
RE: Limiting Oxygen Concentration
Good luck,
Latexman
RE: Limiting Oxygen Concentration
The minimum concentration of oxygen to propagate a flame by the energy generated in the reaction is the basis for inerting and is called the MOC. Inerting is used to bring the oxygen content to at least 4% points below the MOC.
In the absence of experimental data the procedure explained by Latexman can be used as an estimate that has been confirmed to work for many hydrocarbons.
Published LFL (low flammable limit) values for vapor-air mixtures are generally based on the fuel gas in air at 25oC and 760 mm Hg.
For many organic compounds it was found that the LFL can be approximated by taking 55% of the stoichiometric molar concentration of the fuel in the vapor-air mixture.
Visiting the following threads may add more information:
thread135-73870
thread798-47819
thread816-58335
RE: Limiting Oxygen Concentration
I would point out that LOC is affected by the material used as a diluent. For example, according to NFPA 69 the LOC for propane is 11.5% for a N2/air environment, the LOC for propane is 14.5% for a CO2/air environment.