Dcarr:
Most overbuilt cold roofs are vented so that if & when they do leak, they also have some chance of drying out. And, there is often some form of roofing on the lower plane of sheathing so it will drain water. But, they are also generally two parallel planes so the overbuild framing is fairly clean and simple; unlike your’s where all the blocking for the overbuilt sheathing will be of varying depths, plus the trusses having such varying web members, and their costs, whatever. It isn’t that it can’t be done, but it ain’t gona be cheap or easy either. I’d do some serious cost comparisons to see that the sloped insulation is truly more expensive and less complicated.
I would pay particular attention to flashings, venting and vapor barriers in these built-up roof areas, so you’re not just growing hoarfrost and mushrooms in that space. Then, I would put this all in a registered letter for the file and to the Arch. and client, so that you are on record that they are responsible for this approach if & when things do go south.