One thing I did was to map the Pro/E shortcut on each user's machine to a DOS batch program on the network. Each time a user started PRO/E by double-clicking the shorcut icon, the batch program copied CONFIG.SUP, CONFIG.WIN, ENGLISH.DTL, and the company standard CONFIG.PRO to the user's startup directory. There may have been a few other config files copied that I just can't remember at this time.
This system is nice because it insures that each user starts with the same basic settings (the settings are imposed at the start of each session).
Consider if you mapped a network drive called G: on each user's machine. Then assume you had a directory called G:\PROE_CONFIGS that contained the files. The basic DOS commands would be:
>COPY G:\PROE_CONFIGS\*.DTL C:\your path name\*.DTL
>COPY G:\PROE_CONFIGS\*.PRO C:\your path name\*.PRO
This requires that Pro/E be installed identically on each machine (e.g. with the same directory structure and local drive designation C

and requires that each machine use the same letter for the network drive.
Your System Administrator may want to spice it up a bit but these are the basics for implementing such a low-tech (yet effective) system. Of course, if you have INTRALINK or other Pro/E file management utility, that utility may already have this functionality built in.
Tunalover