Latexman and dcasto:
Be cautious with these kind of solutions.
Normally, if you have two valves in a single pipe, they are used (as unclesyd described in his real life example) as double block and bleed to assure a positive blocking of a pipe or equipment. Using a check eliminates the risks of thermal expansions, but the possibility for an operative mistake increases. They can forget the check existence, get the false idea of having blocked the system with a single valve. The Operation Procedure must be revised, to assure the use of both valves, in this case. And take into account that a check valve never assure the blocking for a reverse flow.
process440: Another issue that was not mentioned here is the selection of the set pressure for the Thermal Expansion Relief Valve (if this is the final solution). It should be specified as high as possible, like 1.5 times the design pressure of the equipment being protected (depending on local codes). This is to avoid unexpected releases.
For your specific case, why do you have a double block? This is the question...
Regards
jalvarez