I have written an excel calculation that solves the simultaneous equations involved and can run some cases for you if it helps. You will need to give me all available information on the fluids, pipe, surroundings and environment.
Fluid
Description, Temperature, Density, Heat Capacity, Conductivity, Viscosity, Flowrate.
Pipe
Description, Material, Diameter, Wall Thickness, Length, Outer Surface Condition
Environment
Air Temperature, Solar Radiation Level, Proximity of any buildings or structures, temperature of surroundings.
If you don't have everything I will guess a value.
My calculation can easily run several cases to test sensitivities to varying conditions. It will find rate of heat transfer and temperature rise as well as the equilibrium temperature.
Don't take too much notice of the black pipe or reflective coatings as they will only work short term. The smallest layer of oxidation or dust will quickly change the performance.
Don't ask for the software though, it took a long time to develop and is not available for free. I will need an email address to forward the results in pdf format as I can't post attachments here.
Dennis Kirk Engineering