You're doing a substation. Can you get the utility's distribution standards? They'll have a bunch of standard sag install charts and design tensions that you can use.
Manually making sag charts on your own is a pain in the ass. It's only a single span, so it's not terrible. You mentally seem to be approaching this right. Pick a trial sag or tension. Calculate the length of the line. Decide on the design temperature difference. Apply that and determine the new reduced length of the line and, from that, the sag geometry. Apply the weight of the cable, plus any other design conditions (wind, ice, birds). For tension purposes you can conservatively just pretend the wind is a downward force on the same catenary. Calculate the resulting tension with your various load cases at the reduced temperature geometry. You can either use the first solution, which should be conservative, or you can incorporate tension elongation of the cable into it and iterate. The loaded condition will give you your design tension. If you don't like the answer, pick a different trial sag or tension and do it again.
Now you get to make an install sag chart. Take your initial cable length and recalculate at some regular temperature interval (every 10 degrees, say). Calculate the sag, cable length and tension at each of those values and chart them so that the design conditions for any given temperature are known.