You should design the tank with the same standards as a potable water tank.
Storage tanks should not normally overflow. High alarm level on a tank is typically set at 90% full. The overflow is a contingency in case of failure to shut off the incoming water.
If you regularly drained water to the storm sewer, then you should dechlorinate. For an emergency occurence, it probably does not matter.
The overflow to drain connection should not be hard piped since you may be creating a cross connection.
"Overflow: Provide a ____ mm ____ (inch) steel pipe extended to grade with an overflow visible before spilling into a storm sewer inlet. The overflow shall be provided with an insect screen."
"Guidance: It is recommended that any discharge lines from tank overflow or drains be sloped for complete drainage so as to prevent any standing water in these lines. It is also recommended that these lines be separate from each other as well as separate from other discharge lines, such as from perimeter french drain system, and each be easily visible as required for the overflow line."
"If a drain is provided, it shall not discharge to a sanitary sewer. If local authority allows discharge to a storm drain, the drain discharge shall have a physical air gap of at least two pipe diameters between the discharge end of the pipe and the overflow rim of the receiving basin."
R309-545-13. Tank Overflow.
All water storage structures shall be provided with an overflow which is discharged at an elevation between 12 and 24 inches above the ground surface with an appropriate air gap. The discharges shall not cause erosion.
(1) Diameter.
All overflow pipes shall be of sufficient capacity to permit waste of water in excess of the filling rate.
(2) Slope.
All overflow pipes shall Be sloped for complete drainage,
(3) Screen.
All overflow pipes shall be screened with No. 4 mesh non-corrodible screen installed at a location least susceptible to damage by vandalism,
(4) Visible Discharge.
All overflow pipes shall be located so that any discharge is visible,
(5) Cross Connections.
All overflow pipes shall not be connected to, or discharge into, any sanitary sewer system.
(6) Paint.
If an overflow pipe within a reservoir is painted or otherwise coated, such coating shall comply with ANSI/NSF Standard 61.
R309-545-14. Access Openings.