Honestly, I have a spreadsheet that does both at once to avoid arguing with checkers.
That being said, Chapter 13 is for non-structural components and their supports. If your frame is reasonably small in scope and is just there to support your panels, then it's the support. The supporting structure is the ground. They've updated ASCE-7 to further clarify this. Table 13.6-1 has coefficients in ASCE-7-22 for support frames and there are clauses about them. I haven't used these new values, but a quick glance at the coefficients has me expecting that it's going to spit out values higher than treating it like a non-building structure.
The percentage thing is intended to make sure you aren't doing something that screws up the implied model. The non-structural component formulas are assuming that you've got a small weight component inside a heavy building. The building is the source of the applied acceleration and the component doesn't significantly effect the motion of the building. Once you get to a certain size of equipment, that's no longer the case. The big issue being if there's dynamic interaction and multiple modes happening because of it.
This is not the situation with a piece of equipment and a small scale support, where they'll generally be in a single mode together. Basically, you've gone out the other side of it, but also the consequences aren't a huge deal when you're just looking at the support. If you use the 25% thing for purpose made supports, then you start getting weird situations like every pipe support is a non-building structure.
It's still a judgement call on when to switch to non-building structures, because obviously you're going to treat a large tank four stories up on braced legs as a non-building structure of some sort not a non-structural component on a support but honestly you're doing some sort of first principles evaluation whenever you're looking at that kind of thing anyway.