I usually stick with 60°C as a target temperature for water.
You could potentially use Sic vs. Sic at those temperatures. You most likely know the cost adder for a Sic rotating face will be much more than a carbon rotating face. A more thorough analysis should be done if you want to go this route. A reputable seal manufacturer should be able to help you in this area with regards to analysis and predicted performance under your process conditions. If your's can't go elsewhere.
Be careful with the direction in which you will be pressurizing the hard faces (if you use them). Hard faced combinations which see ID pressurization, such as in the inboard seal of a dual pressurized seal, tandem mounting, will tend to diverge with respect to the barrier pressure. This means the face profile will be concave with respect to the process fluid and you will not be getting barrier fluid across the inboard faces - it will be pinched off, so to speak. OD pressurization on dual seals with hard faced inboards are preferred in my opinion. Just some food for thought.
You may also want to consider a graphite impregnated Sic vs. Sic for your face combination. This material offers the best of both worlds as it will withstand abrasion but also be tolerant of sporadic lubricity. The upper PV limit for this particular face combination is very good and rivals carbon vs. Sic. Unfortunately, cost will most likely still be a factor with that material as well.
An upstream pumping design with hard face materials may also be an option, provided excessive water consumption into the process is tolerable.