reaction of cianyde oxidation

[elcaco]

Is there any literature or article with the values of their kinetic constants, k1, k2 and K3.

Or is there some method to do this ...

I would like to simulate this reaction in Matlab and needed to meet the mandatory provisions contained values ..

Is it possible to determine, k1, k2 and Matlab K3 by knowing the following facts of the case:

Concentrations of cyanide total (NaCN) --------------(in)
cyanide-concentracaoo of the total output (NaCN) ----(out)
hypochlorite-merger of the entry (NaOCl) ------------(in)
-concentration of caustic soda to entry (NaOH)-------(in)
Reaction-time----------------------------------------(time)


Taking into account the reactions of oxidation of cyanide,


k1
NaCN +NaOCl + H2O-----> CNCl + 2 NaOH

k2
CNCl + 2 NaOH -----> NaOCN +NaCl +H2O

k3
NaOCl + NaOCN + H2O -----> NaHCO3 + N2 + NaCl


thanks;

elcaco

 

[chemicalengineerthai]

Better take experiment, it is much better than trial calculation.

your titration and measure temperature and correlate back we short your evaluation.

hope this help.

 

[786392]

I suppose KMno4 i.e Potassium Permangate solution should oxidise check/google with this reference '6860'hits obtained

Best Regards
Qalander(Chem)