Some general advice is possible, but without knowing more about the form of structure to be made it's hard to be genuinely helpful.
Pultrusion with unidirectional fibres can give 70% fibre volume fraction, which will give the greatest rigidity (stiffness) for a given bar size with deformation along the bar axis (bending or axial). Pultrusion isn't really that well suited to producing sheets and is a bit limited for non-unidirectional fibre direction options.
Vacuum injection (VARTM, etc.) is more suited to somewhat lower fibre volumes (often 50-55%) and large sheet areas, with preference usually given to cloth and non-crimp fabric reinforcements, though small fitting-like components can also be infused economically.
The two manufacturing methods are sufficiently different that usually they are not considered alternatives for a given form of structure.
An exception might be beams of constant section such as those sometimes used in truck beds.
What are you making?