Thermal Relief Valve (TRV) is to protect the system (normally pipeline/piping and heat exchanger) due to thermal expansion. TRV is required for the blocked in piping which contain LIQUID and the volume of liquid contains is more than 500 l AND it is exposed to the environment higher than the operating temp of the contain fluid. E.g. if the operating temp of blocked in fluid is 25 and ambient temp is 35, then TRV is required. Otherwise, TRV is not required. TRV is also required if the system is heated by mean of heat tracing (either by steam or by electric).
Size of TRV normally is 1/2" x 1" or 3/4" x 1". 1 deg C temp increase would increase press of up to 100 psi!.
PSV for fire is normal PSV (spring type or pilot type) and with the overpressure of 21 % (unless not permitted by local code). PSV for fire is to take into account the external heat due to fire (pool fire or else) into the system. Please refer to API RP 520 pt 1 and 521.
Hope this help.
Rusman
man@rwsb.po.my
Process Consultant