Interestingly, my experience with governor controllers is somewhat the opposite - I have had nothing but problems with PLC-based governors, and very good experience with dedicated governors.
The PLC-based units tend to offer enormous flexibility in terms of what they can do, which in my experience only tempts people to use this flexibility - this results in the use of unique governor solutions for different sites. Because of this, the user manuals tend to be more general making the governor harder to support unless very familiar with the program (lots of vendor support required!). I've also had a lot more issues with faults, although I suspect that this may be more due to PLC firmware bugs etc than issues with the governor controller per se (all of the PLC-based solutions have been on the same PLC platform).
In comparison, I've found that the only dedicated governors that I've used (Woodward 505H, in multiple sites with several different utilities), while inflexible, steered the plant designers into a simpler, more robust design; have been much more reliable in terms of hardware and software bugs; and are simpler to configure etc, with better documentation.
I have not worked with a DCS-based hydro governor to compare.