One cannot and shouldn't argue against facts: Montemayor's rich experience in compression of many gases, especially when he says that practical experience has corroborated the fact that enthalpy differences on isentropic compression reflect the work of compression. The opposite Scipio's experience that on cooling a sour natural gas (mixture) the work of compression was actually reduced, if true, should be analysed.
Refinery people, and I counted myself among them, think that compression work in piston reciprocating compressors is quite insensitive to relatively small changes in suction temperature, or density, or MW of gases, keeping all other factors constant.
This is based on the assumption that real gases behave in practice as ideal gases. It is true that temperature and density changes cancel out in narrow ranges, but this is not the case with regard to k=Cp/Cv. One should remember that the theoretical adiabatic work of compression is proportional to
[k/(k-1)]*(r(k-1)/k-1). (r is pressure ratio).
Most real gases show an increase in k with a drop in temperature. This fact alone, using the above formula, would explain the small increase in work of compression when cooling the suction.
The change of k values for air or nitrogen at atmospheric pressure below 300 K is quite small thus, based on this fact, the increase in work of compression by pre-cooling them would be indeed small.
Hydrogen and helium have a peculiar behaviour, helium doesn't change its k value on cooling at atmospheric pressure, hydrogen's k drops with temperature, a fact that would result in a reduction of power on cooling the suction. (Art Montemayor: this happens for 100 and 60 deg F, compressing pure hydrogen between 300 psia and 750 psia, even when using enthalpies and mass flow rates following your method, please comment).
Other indirect factors may affect power consumption. Let's mention among them, valve flutter, oil viscosity, and valve leakage. Would a lower temperature affect them, and as a result, change the compression work? Would compressing a cooler natural gas affect the lube oil's viscosity by dissolving light hydrocarbons, the friction at the compressor moving parts would drop, thus reducing power consumption? I wonder.
We are dealing with real-life machines. The actual compressor's internal pressures aren't those measured upstream or downstream, but lower and higher, respectively. The expansion and compression steps aren't truely adiabatic.
If, for example, the compressor is partly unloaded by a head-end clearance pocket, what would be the real temperature of the gas undergoing compression?
The estimates presented by Montemayor show small percentual increases -though not negligible- in power consumption on cooling the suction to CO2 reciprocating compressors. The smallness of these variations may be one of the reasons for the generally accepted viewpoint held by refinery people that the work of compression (mainly for for air and hydrogen-rich gases) in reciprocating units is practically insensitive to suction vapours' density or MW while all other process parameters are kept constant.
It would still be of much interest to hear other opinions.