One way to check the validity is to compare with the ABD matrices.
PCOMP uses matrices that are proportional to the A, B, and D matrices. The resulting PSHELL points to the following four material stiffness matrices;
MID1 which is A divided by plate thickness (T),
MID2 which is D divided by plate inertia (T^3/12)
MID3 which is a transverse shear 2x2 material stiffness matrix,
MID4 which is B divided by T^2
Warning: if you are applying thermal gradients to an unsymmetric layup, then the Nastran composite MIDi numbering scheme used must be followed if you are creating the MAT2 A terms for the above matrices yourself.
Otherwise you can use any numbers for the MAT2 ids.