Frankly, I think that it's bad idea. The vacuum jacket is designed to eliminate all conductive thermal paths. There is no material that can do as good a job as a vacuum for insulation. Whatever material you pick will substantially degrade the thermal insulation of the vacuum jacket. The only material that might come close in thermal properties is a sol-gel, but those are not designed for structural strength.
If there is shock problem, you really should look elsewhere to solve the problem, either with a larger gap, thicker walls or materials, etc.
TTFN