Oil and water don't really mix much. The C4 and heavier molecules have a strong attachemnt for glycol, not water. This is the reason that the reboiler overhead has such a disproportionate BTEX content (2% C4+ in the stream can become 90% of the non-water in the reboiler exhaust, the EPA is currently writing regulations to "fix" this). Stuff smaller than C3 doesn't get absorbed by the glycol as much and when it is in the reboiler it is because something hicuped and belched some gas into the rich glycol.
As to condensing, isoPentane has a boiling point of 88F, so there is a chance that it could condense in the process that the OP mentioned. n-Hexane boils at 155F so it is almost certainly going to condense. The thing is, the reboiler overhead is well over 95% water vapor, so compressing it without going through a condenser first is very risky (especially with a PD compressor, a dynamic compressor might be able to deal with it for a while).
When I had a project that made me think about this I proposed a steam jet ejector to boost the reboiler exhaust a couple of ratios in front of a condenser so I would have some pressure in the non-condensibles to start with (if you can't vent them you have to boost them even into a flare). That project didn't fly for a lot of reasons so I never knew if it was really a good idea.
David