If the LNA was made for any consumer or general commercial work, it is most likely a woven glass/epoxy or FR4. The term "FR4" has beecome a rather generic name. There are specific brands of glass/epoxy with a variety of dielectric constants and other material properties, but generally they have a dielectric constant of 4.2 to 5.5 . Color will generally be green, light-green, or slightly yellow.
Now, if it's for a bottom-end consumer throw-away made as cheaply as possible in high volume out of China, it might be made out of phenolic. Yes, I've seen ultra-cheap low GHz range done in phenolic. Color is generally brown to dark brown.
Now, if the board was made for high-end test equipment, high performance/low noise, or higher temperature application it could be one of a variety of teflon substrates - but this is rare. You will also find teflon (or some Rogers equivalent) in some TV satellite dish antenna LNAs. Color is generally tan to white.