... size? Somhow I believe you are talking about fairly large valves, perhaps above 24 inches? Smaller?
For this aplication in Europe, depending on placement/exact service and size, at least for 24 inches and below, a typical modern replacement would be gatevalves with complete rubber-lined gate, body in nodular cast iron, epoxy coated body and top inside and outside (250-300my), selected from top-quality producers and top models.
A good alternative is high-quality knife-gate valves (ss quality knife, nodular cast iron housing, epoxy coated (also here certified surface coating)) which would also be chaper and lighter for sizes 12 inches and up, and if actuated.
Other alternatives for new valves exists, and complete new valves and pipeline should anyway be considered as an alternativ to repair, with cost/lifetime calculations for complete renewal alternatives compared to overhaul and repair.
Apart from this, I do not think you will have problems with your material combination, repair done properly, but I could be wrong. This is more a material/metallurgical/corrosion problem. You could perhaps try to present this in a material-oriented forum?