Sorry, I forgot your other request, you can position the bolt in a variety of ways.
To constrain use the coincidence command and pick the centreline of the bolt and bolt hole, or the surface will do. Then use the contact constraint and use the surface of the flange and the underside of the bolt head. Depending on your settings the assemblly may update in real time, if not you have to force an update, look for the black & white swirl Icon.
I use the functionality of the compass to get close then finally constrain, in other words drag the compass onto the bolt, Select the bolt in the tree to make active then press left mouse button and drag / rotating along the desired compass axis / plane, when close drag compass back into position using just left mouse drag, best to deselect bolt first.
My best advice if you are new is to obtain training, otherwise you will not unlock the true power or potential of Catia V5...