This is one of those areas where I only know enough to know that I should consult with someone who knows more than I do.
Definitely something that needs to be engineered, not left to the installation contractor to slather on some goop. And yes, copper is a horrible choice here.
The aluminum is probably anodized.
The galvanic potential of aluminum varies quite a bit with grade, and so far we don't know the grade.
The bolts are probably plated, and the plating is probably zinc.
Since this is a window washing track there will be chemicals involved. Those chemicals will most likely be alkaline, and if intended to be mixed with water will be mixed at a much higher concentration than instructed on the bottle.
When the probably zinc plated bolts are tightened down on the probably anodized unknown grade aluminum the anodized film will probably crack locally, causing potential sites for highly localized galvanic corrosion to occur.
The probably zinc will corrode preferentially to the aluminum, which is probably the preferred situation. However eventually enough thickness may be lost to allow the bolt preload to go away, which is probably not a really desirable failure mode.