The basic woven or unidirectional ply of carbon/polymer composite is orthotropic, as are most laminates made using such plies.
There are some subtleties to do with 'coupling' between the forces deforming a laminate and the deflections the laminate undergoes in response. For instance if the number of +angle plies is not equal to the number of -angle plies then 'shear-extension' coupling is present, so the laminate will shear a bit when stretched. This also happens when a laminate shrinks on cooling down from elevated temperature cure or infusion with a hot thermoplastic.
Balancing 90° UD plies on each side of the lamninate centerline is also important. If a 90° ply is opposite a 0° ply the laminate will undergo extension-bend coupling. In fact because a (0/90) laminate is (90/0) when looked at from 90° it will undergo extension-bend in the opposite sense at 90° to the sense at 0°. This means a (0/90) laminate will become saddle-shaped when it shrinks in both directions on cool-down. This is also true of a single ply of harness satin weave, a ply of which is about 80% like a pair of (0/90) plies of UD.
With unidirectional plies you also get 'bend-twist' coupling. This is even if the number of +angle equals the number of -angle ones.
[tt]
<---
1 ///////// + angle 2 \\\\\\\\\ - angle | Moment M
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3 \\\\\\\\\ - angle /
4 ///////// + angle /
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Ply 1 is in compression and will shear out of the page a bit, ply 2 into it a bit less. Ply 3 is in tension and will shear the opposite direction to ply 2 the same amount, ply 4 the opposite direction to ply 1 the same amount. This gives a couple, so all practical UD laminates twist a little bit when bent, even when balanced. Note that the way a harness satin ply is like two plies of UD at right angles means that HS woven material laminates will do this a bit too.
As a laminate cools it shrinks in thickness by about 30 microstrain per kelvin (through-thickness thermal strain is dominated by the resin which is typically about 80 microstrain/K). If the laminate is curved the carbon fibres at the inside and outside are moved closer together, but they don't change in length themselves (they would need to shrink in length the same 30 microstrain/K to stay the same shape). This means that laminates tend to increase in curvature as they cool. This is 'spring-in', and is one of the defining characteristics of making things out of carbon. (It happens with glass too, but a bit less.) Traditionally this is allowed for by experience and making tools which can be changed after the first-off part is assessed, i.e. trial and error.
Occasionally it is desired to have bend-twist coupling, for instance with the forward swept wings of the X-29. In this case the whole wing structure needed the coupling, which meant that the top skin needed to shear one way when the bottom skin sheared the other as the wing bent. This needed skin laminates with entension-shear coupling.
Generally coupling is a bad thing. With sensitive structures like an optical bench or telescope, to remove all coupling needs tweaking of the thicknesses of plies of different angles. When this is done a laminate that is very nearly orthotropic or quasi-isotropic can be made.