Thanks to all of you who've taken time to reply to my post. Having read through some previous posts (on unrelated automotive topics), I now realize that my question was a little vague.
To ivymike, MaxRaceSoftware and TheBlacksmith, I too know of cases where people have been lucky when a gas leak spills on the exhaust or HT system and cases where they haven't.
Evelrod, thanks for your reply. Can I ask if that was a race or road car? (higher temp exhaust I'd guess for a race car) Also, in all your years of engine building and racing, is that the only case you know of?
buzzp, your second case happened to a buddy of mine - he wasn't quick enough to put the fire out and the car was wrecked! In the first case you mentioned, was that an engine oil leak that did the damage? Most relevant to the current question (see later), did your insurers pay out?
Ok. Now to phrase the question a little more specifically (and scientifically). A buddy of mine had an underbonnet fire which wrecked his car back in Nov 2000. His insurers claim that the fire was caused by a leak from the rocker cover gasket onto the exhaust manifold and that, as he couldn't provide service records, they weren't going to pay him.
I've spoken with a guy who was in the fire service for 24 years who claims that the leak alone couldn't cause the fire. To help my friend out, I'm trying to find out if it is (scientifically) possible for the leak to cause the fire.
Here's the results of my investigations so far: the flash point of oil (which I think means the temp at which it will ignite IF provided with a spark - please correct me if I'm wrong) is around 200 degrees centigrade. Below that temp, you can heat it up and wave sparklers near it and it'll be ok (compare with gas, which at room temp will go BOOM when the spark ignites the fumes).
I measured the temp of a friends ex manifold (a diesel taxi) and it turned out to be 55 deg C - admittedly, the car hadn't got to full operating temp.
Hope the above clarifies my question. Once again, thanks to all who've helped out.