The sheet metal program could work for unfolding the sheet into flats. However, the sheet metal program would not prevent you from designing structures which would not inflate to the shape you designed.
If you are an experienced inflatable designer, I am sorry for belaboring the obvious, but I guessed that this thread might be found on a search by someone who isn't so experienced. For the latter:
Since inflatables are strictly tensile structures, they will always have a cross-section which is circular. I can't even begin to tell you the number of designs I saw that featured flat surfaces and square corners which were intended to be maintained in that shape by internal pressure. Perfectly acceptable sheet metal design, totally bonkers as inflatable design.
Another thing that makes sheet metal patterns different than inflatable patterns is the strongly anisotropic nature of most materials used for inflatables. Sheet metal is almost the same in all directions; certainly it is more so than square-woven nylon with urethane coating. So, you will have to watch the warp direction of the fabric and tweak the shapes to allow for stretching on the bias.