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Forgot to mention that the Ph of our water was low and we had to use an inhibitor to raise the ph to 7-8.

water and methanol combination can also have organic acids. We found a reboiler to a methanol tower that the inlet nozzles took the brunt of the corrosion but the return line to the methanol tower which was MS was wiped continualy by the vapour and did not form a rust film had excelerated...