Best practice is to set the PSV at MAWP, and if two PSVs are installed, one at MAWP and the 2nd at 105% of MAWP, per API 520. MAWP is already such a conservative number (about 1/3 of yield point) that lowering your set pressure by 5-10% below MAWP won't help the process, but now you run the risk...