Viscosity Correlation Calculation
Viscosity Correlation Calculation
(OP)
Hello,
I would like to have some sorts of correlation to calculate the Viscosity at different Temperature, since we measure our Viscosity for Heavy Fuel Oil @ 50 °C.
I would like to know the expected viscosity at 100 °C. Thank you.
I would like to have some sorts of correlation to calculate the Viscosity at different Temperature, since we measure our Viscosity for Heavy Fuel Oil @ 50 °C.
I would like to know the expected viscosity at 100 °C. Thank you.





RE: Viscosity Correlation Calculation
RE: Viscosity Correlation Calculation
In order to be able to find viscosities of fuels at various temperatures one needs to know two viscosities at two different temperatures.
By using charts such as the BP viscosity/temperature chart or the Refutas chart one can find the wanted value at other temps. This is needed since the VI (viscosity index) of the fuels isn't known. The VI or V/T dependence varies with chemical structure of the hydrocarbons. You probably heard of paraffinic (high VI) and naphthenic (low VI) lubes.
The BP chart, for example, enables converting among various viscosities such as Redwwod I, Saybolt Universal and Saybolt Furol, all of them measured in seconds, to degrees Engler or to kin. visc. in cS. One can use either oC or oF. The BP chart is helpful in making blends on a weight basis.
One can also use the ASTM Standard Charts for Liquid Petroleum Products (D341) that give kinematic viscosities vs temperatures. There are charts for low and high viscosity ranges.
Perry suggests for visc. blending of non-polar liquids:
ln viscblend = summation of (wi x ln visci) with a 5-10% precision,
where wi = weight fractions of the components.
Coming back to your question, measure the viscosity at another temperature, and then extrapolate or intrapolate as needed to get the value at 100oC. Kinematic viscosities appear to be loglog dependent on temperatures.
RE: Viscosity Correlation Calculation
However, there is a program available from Det Norske Veritas Petroleum Services in Holland which is free and which allows you to calculate all sorts of related factors. Sorry, you'll have to find their contact details from their web site.
You can also go to www.steamesteem.com where there is a shareware program you can download.
RE: Viscosity Correlation Calculation
The function we have found to be the most reliable for everytiing from quench oil to bitumens (asphalts) is the ASTM D341 equation log10.log10(v +0.7) = A-B log10(T+273) wher V is kinematic viscosity in cst and T is the temperature in degC.
When it comes to fuel oils we have seen all sorts of functions used with widely differing results!
RE: Viscosity Correlation Calculation
If you are blending fuel and measuring viscosity at 50degC i presume you are using the Hoffler falling ball viscometer and a hydrometer method. These can give good results but by the time you get them, it is often too late. Then too you are basing your calculations on samples. Samples are a problem. Spot samples are unrepresentative. The same applies to the three samples taken during bunkering (begining middle and end) which are averaged. Continuous viscosity measurement online revealed a significant viscosity variaton during blending which suggested that the required standard of 180 +ocst -10cst was not easily met. Continuous drip samplers tend to be biased toward a lower apparent viscosity because they generally tend to collect more sample at lower viscosity.
A number of bunker suppliers we have spoken with report that calculations based on the assumed viscosity of the fuel in the storage tanks can vary significantly due to stratification. Overall, the cost per ton of heavy fuel oil due to inaccurate blending based on calculation is more than $3. Not insignificant.
You may care to visit some other sites such as www.chl.chalmers.se . They have some studies based on fuel delivered over a two year period to a ship. CBI Engineering in Denmark produce fuel blenders as do ALBA shipping. Also, www.Jiskoot.com And www.VAF.nl