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vapor pressure

vapor pressure

vapor pressure

(OP)
the vapor pressure of ammonia and water increases with temperature.  if this solution is in a metal tank in the sunlight, and the solution temperature rises, will the actual tank pressure increase with the vapor pressure?

RE: vapor pressure

Yes!  Perry's has data on the total vapor pressure of various concentrations at various temperatures.  It is not unusual for 28% NH3 solution in a tank to be at it's boiling point in the summer.  That's why aqueous ammonia storage tanks should be pressure vessels.

Good luck,
Latexman

RE: vapor pressure

Would it be true that until the ammonia boils, the tank remains at atmospheric pressure?

RE: vapor pressure

It really depends on how the tank's venting is set up, but most likely the answer is yes.  I've seen pressure vessels that "ride the bubble" and those would be in a vacuum.

Good luck,
Latexman

RE: vapor pressure

If the tank is vented freely with no back pressure it will stay at atmospheric pressure even at boiling point.  Think of a pot of boiling water.

If the tank has no vent then the tank pressure will be equal to the vapor pressure of the solution inside for the given temperature.

RE: vapor pressure

And conversely, the tank pressure will rise and fall in accordance with ambient temperature swings.

RE: vapor pressure

But if it's vented freely, you won't have any ammonia in the tank when you need it, and all the grass around the tank will be really really green.   

RE: vapor pressure

terry....

Aqueous ammonia tanks with solutions >19% do indeed exist and this is a well known technology.

As I recall, the typical tank is a coded pressure vessel designed to ~30 psig.

Lower concentrations can be handled by a "flat-bottomed" API-650 type tank with a conservation vent.

-MJC

   

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