Resources for nitrogen purging of a vessel for storage
Resources for nitrogen purging of a vessel for storage
(OP)
I'm currently trying to write a specification for nitrogen purging of vessels after fabrication to drive the oxygen level down to prevent corrosion. Do any of you know of some good resources that I can read that will give me a good background in setting an acceptable residual oxygen level and performing the calculations to determine number of purge cycles required to reach that level?
Thanks for your help, guys.
Thanks for your help, guys.





RE: Resources for nitrogen purging of a vessel for storage
RE: Resources for nitrogen purging of a vessel for storage
Chemical Process Safety: Fundamentals with Applications
by Crowl and Louvar. Prentice Hall.
RE: Resources for nitrogen purging of a vessel for storage
Also, is you must prevent moist air ingrease, you just simply add some Nitrogen to the air at 1 - 5 psi and maintain that pressure with some nozzle blanks and a small bottle of nitrogen to make up any loss of pressure.
Sorry, I don't believe that there is any formal written procedure, it is rather a good practice specification developed by the main stream construction companies for transport and long term storage of carbon steel vessels.
Cheers,
gr2vessels
RE: Resources for nitrogen purging of a vessel for storage
The operator who will be purging the vessel should be wearing an air pack and he should have an oxygen sensor which he can use on a vent. When the O2 level is below the limit, the vessel is ready. The idea is to keep purging and checking the oxygen level. Be sure to have people without air packs to keep away from low areas near the purge. Oxygen is slightly heavier than nitrogen so the purging should be at a low point in the piping (ie pump piping vent).
I'd bet one nitrogen truckload should be good enough. Keep the vessel pressurised after purging is complete to check for leaks. Check the pressure a couple of hours after purging. We ended up finding some leaks which would have been a nuisance or a danger.
RE: Resources for nitrogen purging of a vessel for storage
RE: Resources for nitrogen purging of a vessel for storage
Your problem then is to stop air getting back in, are you going to seal the vessel ? If so you have serious problems supplying a vessel full of nitrogen.You will have to formulate handling instructions.
I would rethink your anti corrosion programme if I were you.
RE: Resources for nitrogen purging of a vessel for storage
If the issue is explosion / fire, I read some guidelines on firefighting that suggest that an effective purge and dilution to around 10% O2 is often adequate.
The procedure by Glenfiddich is completely consistent with one we recently developed for post-blowdown purging of sour flare systems where sweet fuel gas is unavailable.
Depending on pressure of N2 supply and ambient temperature during purge, consider a precision glass thermometer or skin temperature RTD downstream of the point of N2 injection. You probably don't want too many prolonged excursions down to or near the nil ductility temperature. If brittle fracture is deemed a risk, consider some length of austenitic pipe between the N2 supply and the system to be purged.
Regards,
SNORGY.
RE: Resources for nitrogen purging of a vessel for storage
Gr2 Vessels: Respectfully disagree that N2 is heavier than air. MW of N2 is 28. 20% of air is O2 with Mw of 32. That makes the effective MW of air very close to 29. so N2 is 97% as heavy as air. Unless you are in Houston in July, where there is so much water vapor in the air (MW=18) that it would certainly tip the scales. I really don't think you can count on stratification of the gases, tho', and having condensible water vapor in the tank is a no-no.
Initial purge of the empty tank with a volume of Nitrogen equivalent to the volume of the tank shoud be fine as long as the vent is located in a fairly stagnant area of the tank top and the N2 is introduced gently to prevent agitation/forced mixing/short-circuiting of the N2. Then when the tank is filled the initial N2/Air atmosphere in the tank will be vented off. Any future level/pressure cycles will be replaced with pure N2, so the tank atmosphere will reach an equilibrium of nearly pure N2 in a few days if not sooner.
RE: Resources for nitrogen purging of a vessel for storage
JimCasey,
Just to nitpick - no reasonable combination of temp/ humidity will drop the mol weight below 28.
In my operations group they say in one area they operate the temps reach 122F with 85% humidity - if true this would be the highest ever recorded heat index at 333F (current is 167F) and they should be dead from lack of being able to cool themselves.
I'm in Houston and I hyperbolize about the temp humidity, but I know it's not realistic that we get 100F and 90% humidity like people often say - if we did we'd be in the record books.
RE: Resources for nitrogen purging of a vessel for storage
I have seen humidity of 65% (and I have seen the hygrometer as well) in West Africa with temps of 41C.
Am I missing something here because I never saw any reference to this question being about floating roof tanks ?
I like djv's 4 psi solution
RE: Resources for nitrogen purging of a vessel for storage