meoh storage vessel
meoh storage vessel
(OP)
A quick question regarding methanol and vapor pressure. I am a little confused regarding the relationship between nitrogen padding and vapor pressure. We are designing a storage tank for methanol with a pad/de-pad system. I understand we need to keep a blanket to prevent o2 and air from entering the system for corrosion reasons.
Secondly, nitrogen will pad the vessel during thermal in-breath. But I don't understand, why or how the really low vap. pressure of methanol can somehow lead to a vacuum scenario which is why we have to maintain a positive pressure. At extremely cold temperatures vap. pressure is below 0 gauge. Can anyone clear this concept up for me? Thanks.
Secondly, nitrogen will pad the vessel during thermal in-breath. But I don't understand, why or how the really low vap. pressure of methanol can somehow lead to a vacuum scenario which is why we have to maintain a positive pressure. At extremely cold temperatures vap. pressure is below 0 gauge. Can anyone clear this concept up for me? Thanks.





RE: meoh storage vessel
Oil:
Nitrogen padding in a Methanol tank is not done to avoid corrosion. It is primarily to comply with environmental regulations and safety hazards. The intent of the application is to keep the methanol (vapors) in the tank and pressurized so that air can't invade the vapor space and create a combustible mixture.
The vacuum case can appear in a such a tank through the results of pump out (or drainage) while the N2 makeup supply valve is inoperative due to whatever reason. For this hazard scenario you have the appplication of the usual conservation vent - a relief device that is a combination pressure/vacuum relief valve mounted on the roof of the tank. You can also apply a separate, independent vacuum relief device as well.
The nitrogen vent system should work to maintain the tanks vapor space with a positive N2 pressure, so there is no vacuum produced by thermal cooling - as long as the N2 pad is working. There is no "vapor pressure" to fear - just a sudden vacuum caused by lack of sustaining a positive N2 pressure.
The above only deal with operating conditions. You can "suck in" a tank for other reasons, but you don't mention those.
RE: meoh storage vessel
A tank which never had hydrocarbons in it would still buckle if cooled just from the contraction of N2. Use the ideal gas law and calculate the volume difference of the starting tank mass of N2 as it is cooled from 20C to 0C (as is happening where I am every day/night). That volume difference is how much the tank would have to "contract" if you had no pad.
best wishes,
sshep
RE: meoh storage vessel
RE: meoh storage vessel
RE: meoh storage vessel
best wishes,
sshep